Poly[tetrakis[μ2-1,3-bis(4-pyridyl)propane-κ2 N:N′]dichloridobis(phenylacetato)dimanganese(II)]
نویسندگان
چکیده
In the title compound, [Mn(2)(C(8)H(7)O(2))(2)Cl(2)(C(13)H(14)N(2))(4)](n), the two Mn(II) atoms lie on inversion centers and are connected by the N-heterocyclic ligands into a wave-like lamellar framework structure. One Mn(II) atom is covalently bonded to two Cl atoms and the other to two benzyl-acetate anions; both Mn atoms show distorted octahedral coordinations.
منابع مشابه
catena-Poly[[[bis[2,2′-(propane-1,3-diyldithio)bis(1,3,4-thiadiazole)-κN 4]copper(II)]-bis[μ-2,2′-(propane-1,3-diyldithio)bis(1,3,4-thiadiazole)-κ2 N 4:N 4′]] bis(perchlorate)]
In the title compound, {[Cu(C(7)H(8)N(4)S(4))(4)](ClO(4))(2)}(n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by six N atoms of three symmetry-related 2,2'-(propane-1,3-diyldithio)bis-(1,3,4-thia-diazole) (L) ligands in a slightly distorted octa-hedral geometry. The ligand L adopts two kinds of coordination modes in the crystal structure; one is a monodent...
متن کاملPoly[tetraaquabis(μ3-benzene-1,3-dicarboxylato-κ3 O:O′:O′′)bis(μ2-benzene-1,3-dicarboxylato-κ3 O,O′:O′′)[μ2-1,4-bis(1,2,4-triazol-1-yl)butane-κ2 N:N′]tetrazinc(II)]
In the crystal structure of the title compound, [Zn(4)(C(8)H(4)O(4))(4)(C(8)H(12)N(6))(H(2)O)(4)](n), one Zn(II) atom is four-coordinated in a slightly distorted tetra-hedral geometry by two O atoms from benzene-1,3-dicarboxyl-ate (BDC) ligands, one N atom from a 1,4-bis-(1,2,4-triazol-1-yl)butane (BTB) ligand and one water mol-ecule, while a second Zn(II) atom is five-coordinated in a distorte...
متن کاملPoly[bis(μ2-1,3-phenylenediamine-κ2 N:N′)di-μ-thiocyanato-κ2 N:S;κ2 S:N-cadmium]
The structure of the title polymeric compound, [Cd(SCN)2(C6H8N2)2] n , exhibits a two-dimensional staircase-like structure parallel to (010) in which the Cd(II) atom lies on a twofold rotation axis and has a distorted octa-hedral CdS2N4 geometry involving four μ-1,3-(SCN) group donors and two N-atom donors from 1,3-phenyl-enedi-amine ligands, which also have twofold symmetry. The major contribu...
متن کامل{μ2-1,4-Bis[2-(4-pyridyl)ethenyl]benzene-κ2 N:N′}bis[bis(acetylacetonato-κ2 O,O′)copper(II)]
The asymmetric unit of the title compound, [Cu(2)(C(5)H(7)O(2))(4)(C(20)H(16)N(2))], contains half of a centrosymmetric dinuclear mol-ecule. In the mol-ecule, each Cu center is coordinated by four O atoms from two acetyl-acetonate ligands and one N atom from the bridging linear 1,4-bis-[2-(4-pyrid-yl)ethen-yl]benzene ligand in a square-pyramidal geometry. In the crystal structure, weak inter-mo...
متن کاملcatena-Poly[bis(μ3-2-phenylacetato-κ3 O,O′:O)bis(μ2-2-phenylacetato-κ2 O:O′)dicopper(II)(Cu—Cu)]
The title polymeric compound, [Cu2(C8H7O2)4] n , was synthesized by the reaction of copper acetate with aqueous phenyl-acetic acid. The unique Cu(II) atom is coordinated by five O atoms from the carboxyl-ate groups of phenyl-acetate ligands, and the strongly distorted octa-hedral coordination environment is completed by a Cu-Cu bond of 2.581 (2) Å, at whose mid-point is located an inversion cen...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010